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Growth of $$beta$$-FeSi$$_{2}$$ nanocrystals by phase transition and enhancement of light emission property

西村 健太郎*; 中島 孝仁*; 永澤 良之*; 鳴海 一雅; 前田 佳均*

no journal, , 

Photoluminescence (PL) properties have been investigated systematically for the $$beta$$-FeSi$$_{2}$$ nanocrystals which were formed by controlling the phase transition from the $$gamma$$-phase. Photoluminescence intensity of the FeSi$$_{2}$$ nanocrystals was enhanced by a double thermal annealing in the phase transition process: the preannealing time at 500$$^{circ}$$C surely controls amount of the $$gamma$$-phase precipitated on Si(111), and the postannealing time at 800$$^{circ}$$C dominates final amount of the $$beta$$-phase nanocrystals with coherent interfaces as well as the $$gamma$$$$rightarrow$$$$beta$$ phase transition. It is speculated that the PL enhancement is attributed to the least defective interface between the nanocrystal and Si(111) induced by the phase transition by a double thermal annealing process.

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